#1) Batman
Villan: Joker (Jack)

#2) Batman Returns
Villan: Penguin (Oswald Copplepot)

#3) Batman Forever
Villans: The Riddler (Edward Nygma) and Two-Face (Harvey)

#4) Batman and Robin
Villan: Mr. Freeze (Dr. Victor Fries)

#5) Batman Begins
Villans: Scarecrow and Ducard